(E)-2-[1-(1-Benzothiophen-3-yl)ethylidene]hydrazinecarbothioamide methanol hemisolvate
نویسندگان
چکیده
The asymmetric unit of the title compound, C(11)H(11)N(3)S(2)·0.5CH(4)O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N-H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N-H⋯O, N-H⋯N, O-H⋯S and N-H⋯S hydrogen bonds and weak C-H⋯O, C-H⋯N and C-H⋯S contacts together with an S⋯S [3.5958 (14) Å] and a C-H⋯π inter-action form a three-dimensional network.
منابع مشابه
Tris[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]gadolinium(III) methanol hemisolvate 2.5-hydrate
In the title complex, [Gd(C(11)H(10)N(3)O(2))(3)]·0.5CH(4)O·2.5H(2)O, the Gd atom is coordinated by six N atoms and three O atoms derived from three tridentate monoanionic 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The mol-ecules are linked together via hydrogen bonds involving the solvent water and methanol mol-ecules.
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